Top 10 Starbucksbr Frappuccinos.br The first frappuccino was madebr in 1992 by a Massachusetts coffeebr shop called Coffee Connection. .br Starbucks bought the shop in 1994,br trademarked the frappuccino name andbr began selling the drink nationwide in 1995.br In honor of National Frappe Day, here arebr the top 10 frappucinos from Starbucks. .br 1. White Chocolate Mocha.br 2. S’mores.br 3. Vanilla Bean.br 4. Strawberry.br 5. Green Tea.br 6. Caramel.br 7. Mocha.br 8. Pumpkin Spice.br 9. Java Chip.br 10.