São Vicente (Things to do - Places to Visit) - SÃO VICENTE Top Tourist Placesbr Municipality in Brazilbr São Vicente is a coastal municipality at southern São Paulo, Brazil. It is part of the Metropolitan Region of Baixada Santista. The population is 355,542 in an area of 147.89 square kilometers.br br São Vicente is located on the western half of coastal São Vicente Island, being mostly a bedroom community for the larger and wealthier neighboring port and commercial city of Santos on the island's eastern half.